Enhanced photoreactivity of MOFs by intercalating interlayer bands via simultaneous ?NCO and ?SCu modification

Herein, we propose a novel method to enhance the photoreactivity of an MOF catalyst by grafting isocyanate bonds ( NCO) and sulfhydryl-complexed copper ( SCu) onto ZIF-8 (NIF-SCu). The grafting process intercalated interlayer bands between the conduction and valence bands of ZIF-8, thereby providing a “ladder” for facile electron transition. The extreme improvement in the photoreactivity of NIF-SCu could be attributed to the enhancement in light responses in the range of 350–450 nm by  NCO groups and the widening of the visible light range of the MOF by  SCu groups. The formation of staggered energy levels in NIF-SCu could also narrow the band gap, lower the resistance, and facilitate the transfer of photogenerated carriers, thereby generating electrons with strong reduction potential in the  SCu conduction band. This study provides a new strategy for improving or even endowing the photoactivity of environmental functional materials with wide bandgaps.     

CDBN‑IKELM的轴承变工况故障诊断方法

针对现有方法在轴承变工况方面存在的诊断精度低、人工提取特征不充分等问题，提出了基于卷积深度置信网络（convolutional deep belief network，简称CDBN）与改进核极限学习机 （improved Kernel?based extreme learning machine，简称IKELM）的滚动轴承故障智能识别方法。首先，由卷积深度置信网络对原始信号内的故障特征进行深层自适应提取；其次，利用等距特征映射对提取的多维特征进行降维，去除冗余特征信息；然后，采用改进的核极限学习机对特征进行分类，使用粒子群（particle swarm optimization， 简称PSO）对模型重要参数进行优化，实现滚动轴承变工况下的故障识别；最后，将所提方法应用于不同工况下多种轴承故障的诊断。实验结果表明，该方法能够智能有效地识别变工况的轴承故障，诊断结果优于已有的智能故障诊断方法。     

Elemental analysis of cemented carbides by calibration-free portable laser-induced breakdown spectroscopy

The process of cemented carbides manufacturing requires rapid and field elemental analytical techniques to control and evaluate the properties of products. Calibration-free laser-induced breakdown spectroscopy (CF-LIBS) is such a potential elemental analytical technique. In this work, a portable LIBS instrument combined with a CF method was developed for the analysis of cemented carbides. Three batches of cemented compact carbides without reference samples were analyzed. Qualitative and quantitative analysis of the samples were achieved by using the portable LIBS instrument combined with CF method. To validate the analysis results, X-ray fluorescence spectrometry (XRF) was used to analyze the samples as well. The results of CF-LIBS agreed well with the results of XRF, with relative errors between ?29.53 and 24.70%. The results demonstrated that the portable LIBS instrument combined with CF method was capable for direct and rapid analysis without any need of standard measurements. Notably, with the portable LIBS instrument combined with CF method, acceptable accuracy could be obtained, which is promising for practical field applications.     

A comparative study on pyrolysis reactivity and gas release characteristics of biomass and coal using TG-MS analysis

Pyrolysis reactivity and gas release characteristics of biomass and coals were comparatively investigated using TG-MS. In addition, chemical compositions and structures of tested samples were determined to correlate pyrolysis gas release characteristic. It was found that pyrolysis reactivity and gaseous product release were hardly varied with pyrolysis heating rate. Furthermore, pyrolysis rates of two biomass samples were greater than those of coals, which were mainly attributed to the chemical compositions and the gaseous product evolution process. The result also showed that gaseous product release during pyrolysis process was related to the presence of different functional groups in samples.     

退火温度对新型锆合金薄板带材析出相和织构的影响

采用扫描电镜和超高分辨透射电镜,对具有良好冲制性能的新型锆合金薄板成品带材进行含晶粒、第二相粒子等在内的显微组织研究,并探索真空退火处理条件下温度对带材显微组织的影响。结果显示:新型锆合金薄板成品带材晶粒平均尺寸2.17 μm,存在{0001}<1010>和{0001}<1120>两种织构,大部分晶粒<1120>平行带材RD方向,较少晶粒<1010>平行带材RD方向;第二相粒子分布在晶粒内部及晶界,平均尺寸114 nm,尺寸较大的为不规则椭圆形的Zr-Nb-Fe相,尺寸较小的为圆形的β-Nb相;热处理退火温度降低,带材晶粒尺寸减小,第二相粒子细小弥散分布;新型锆合金薄板成品带材良好冲制性能主要源于轧制积累应变诱发再结晶过程进行充分,导致晶粒细小及孪晶发生破碎;相对轧制变形,退火对带材冲制性能影响不显著。     

电厂节能管理技术措施探讨

随着社会经济的迅速发展,各个领域对于能源的需求也越来越大,在我国倡导的节能、环保、低碳社会发展理念下,相关部门必须加大对提高能源使用效率的研究力度。当前我国的大多数电厂主要以煤炭等化石能源为主,所以,如何有效提高发电厂发电效率和节约能源是电力企业的重要课题,文章对此进行了探讨。     

石墨烯纳米制冷剂核态池沸腾换热的实验研究

为分析单层石墨烯纳米片对核态池沸腾换热的影响机理，对基液为R141b、分散相为单层石墨烯纳米片的纳米制冷剂的核态池沸腾换热特征进行了测定，采用Hot Disk热物性分析仪和铂金板法分别测定了石墨烯纳米制冷剂的热导率和表面张力，采用接触角测量仪和扫描电子显微镜（SEM）观测了沸腾后加热表面的润湿性和形貌特征。实验中，单层石墨烯纳米片的质量百分含量（ω）为0.02%~0.50%，实验压力为一个标准大气压，热流密度为20~200 kW/m2。实验结果表明：单层石墨烯纳米片的加入，使制冷剂R141b的核态池沸腾换热得到强化；当ω=0.2%时，换热系数提高比例出现峰值，为57.7%。伴随ω的增加，石墨烯纳米制冷剂的热导率增大、表面张力减小，沸腾表面润湿性增强且微腔数先增后减，综合作用的结果导致存在一个最佳的单层石墨烯纳米片浓度（即ω=0.2%）使换热系数最高。     

Relaxor behavior and energy storage density induced by B-sites substitutions in (Ca0.28Ba0.72)2.1Na0.8Nb5O15 Tungsten bronze ceramics

Lead-free relaxor ferroelectrics (Ca_0.28Ba_0.72)_2.1Na_0.8Nb_5-xSb_xO₁₅ (CBNNS) and (Ca_0.28Ba_0.72)_2.1Na_0.8Nb_5-yTa_yO₁₅ (CBNNT) with tungsten bronze structure were fabricated via solid-state reactions. The obtained CBNNS and CBNNT ceramics showed different dielectric behaviors. Only the CBNNS ceramics revealed an intensified diffusion and relaxor-like characteristics, which could be verified by the modified Curie–Weiss law. The relaxor behaviors in CBNNS were attributed to the radii difference between Sb⁵⁺ and Nb⁵⁺ ions co-occupying in B-sites. For the substitution of Nb⁵⁺ by Sb⁵⁺ in CBNNS ceramics, the change from macroscopic polarization to local polarization could also give rise to the obvious relaxor behavior. The Raman spectra verified a larger off-centering of the cation and a higher distortion degree for BO₆ octahedron in the ab plane for CBNNS ceramics when compared with those of CBNNT. In addition, the ferroelectric properties of CBNNS ceramics further indicated the relaxor ferroelectric nature, and also confirmed that the relaxor behavior helped to improve the energy-storage performance.